Farmers and gardeners often use mulch films to increase crop yields and regulate soil moisture. The problem with this is that the petroleum-based material used for mulch films is not biodegradable. As a result, at the end of a season, a lot of effort needs to be put in to collect the film residues as leaving them would cause pollution to the soil. Within the scope of the NewHype project, Fraunhofer researchers are working with European partners to develop sustainable, biodegradable mulch papers with a protective hybrid coating.
The residues of films made from petroleum-based polymers – especially polyethylene – remain in the soil for several decades. Since they are not biodegradable, they accumulate there and pollute the land. Although they are collected at the end of the season, this requires a lot of work and is not usually entirely successful. When the film residues decompose into microplastics, they may eventually enter the food chain. In response to this and within the framework of the NewHype project, a team of researchers at the Fraunhofer Institute for Silicate Research ISC in Würzburg, together with research and industry partners from Germany, Finland, and Norway, has developed biodegradable, sustainable alternatives.
When it comes to finding an environmentally friendly substitute for the large films, there is an important condition that must be fulfilled – any replacement must be both cost-effective and easy to mass produce.
Biodegradable paper as an alternative to plastic films
For the development of sustainable films, the project partners opted for cellulose-based paper. This has the advantage of being able to decompose quickly without leaving residues. However, this also means it decomposes too quickly to be used directly. Accordingly, a protective functional coating made of ORMOCER®s was designed to stabilize the paper and slow down the decomposition process so that the films are able to withstand rain for longer than just a few downpours and can be more easily spread or applied by vehicle. The ORMOCER® class of materials was developed at Fraunhofer ISC more than 30 years ago and offers chemical and mechanical stability due to the hybrid inorganic-organic character of the materials. The mulch paper has been designed to remain stable for the length of a three to six-month growing season, after which it decomposes completely. Initial tests have proved that coating the paper massively increases its wet tenacity, making it more stable than its uncoated counterpart.
A composting test also showed that the coated material degrades more slowly, but, crucially, does still decompose.
Novel hybrid mulch paper
In addition to this stabilizing functional coating, the project partners are also working on a completely new hybrid mulch paper made from functionalized nanocellulose with ORMOCER® bonding. What makes this paper special is the fact that it will not require any additional coating and – thanks to its biodegradability – could be simply plowed into the soil after use, just like the coated mulch paper.
Fraunhofer ISC is responsible for the coordination, administration, and management of the entire NewHype joint project. Thanks to its many years of experience and expertise in the field of coating development, the institute is also responsible for the development, modification, and characterization of the hybrid coating materials – the ORMOCER® class of materials – and for combining these with the cellulose-based base materials.